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Particle Number (PN) measurement testing has for long been conducted by using Condensation Particle Counter (CPC) based technology. While accurate at low concentrations, CPC has nevertheless several drawbacks for in-field use, such as the use of a working fluid, the need for dilution, the delicate optical components and the sensitivity to contamination. Diffusion Charging (DC) based particle counting technologies have often been disregarded as a valid alternative to CPC based methods due to their intrinsic particle size dependent counting efficiency and lower sensitivity. However, Dekati’s novel ePNC PN technology has brought DC technology to the next level.

The trend towards renewable energy sources will continue under the pre-amble of greenhouse gas (GHG) emission reduction targets. The main question is how to harvest and store renewable energy properly. The challenge of intermittency of the renewable energy resources make the supply less predictable compared to the traditional energy sources. Chemical energy carriers like hydrogen and synthetic fuels (e-Fuels) seem to be at least a part of the solution for storing renewable energy. The usage of e-Fuels in the existing ICE-powered vehicle fleet has a big lever arm to reduce the GHG emissions of the transport sector in the short- and medium term. The paper covers the whole well-to-wheel (WtW) pathway by discussing the e-Fuel production from renewable sources, the storage and the usage in the vehicle. It will be summarized by scenarios on the impact of e-Fuel to the WtW CO2 fleet emissions.

Reduced emissions, improved fuel economy, and improved performance are a priority for manufacturers of internal combustion engines. However, these three goals are normally interrelated and difficult to optimize simultaneously. Studying the experimental heat release provides a useful tool for combustion optimization. Heavy-duty diesel engines are inherently transient, even during steady state operation engine controls can vary due to exhaust gas recirculation (EGR) or aftertreatment requirements. This paper examines the heat release and the derived combustion characteristics during steady state and transient operation for a 1992 DDC series 60 engine and a 2004 Cummins ISM 370 engine. In-cylinder pressure was collected during repeat steady state SET and the heavy-duty transient FTP test cycles.

“Zoning” a catalytic converter involves placing higher concentrations of platinum group metals (PGM) in the inlet portion of the substrate. This is done to optimize the cost-to-performance tradeoff by increasing the reaction rate at lower temperatures while minimizing PGM usage. A potentially useful application of catalyst zoning is to improve performance using a constant PGM mass. A study was performed to assess what the optimum ratio of front to rear palladium zone length is to achieve the highest performance in vehicle emission testing. Varying the zone ratio from 1:1 to 1:9 shows a clear hydrocarbon performance optimum at a 1:5.66 (15%/85%) split. This performance optimum shows as both a minimum in FTP75 non-methane organic gas (NMOG) emissions as well as a minimum in hydrocarbon, carbon monoxide, and nitrogen oxide light-off temperature. Overall, an improvement of 18%, or 11 mg/mi of combined NMOG+NOx emissions was obtained without using additional PGM.

In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.

A zirconia electroysis cell is an all-solid state (mainly ceramic) device consisting of two electrodes separated by a dense zirconia electrolyte. The cell electrochemically reduces carbon dioxide to oxygen and carbon monoxide at elevated temperatures (800 to 1000°C). The zirconia electrolysis cell provides a simple, lightweight, low-volume system for Mars In-Situ Resource Utilization (ISRU) applications. This paper describes the fabrication process and discusses the electrochemical performance and other properties of zirconia electrolysis cells made by the tape calendering method. Electrolytes produced by this method are very thin (micrometer-thick); the thin electrolyte reduces ohmic losses in the cell, permitting efficient operation at temperatures of 800°C or below.

Diesel engines are coming under stricter requirements to reduce emissions. particularly those of particulates and nitrogen oxides (NOx). Recently, the U. S. EPA put into place staged requirements for heavy duty diesel engines in urban bus applications which are aimed at ultimately bringing pre-1994 engines into particulate emissions compliance with 1994 heavy duty on-road truck standards (0. 1 g/bhp-hr TPM). This reflects the need to control emissions in crowded urban environments. Zirconia based ceramic combustion management coatings, although originally developed for adiabatic or low heat rejection engines to boost thermal efficiency, have also been shown to contribute to the reduction in diesel emissions. Heavy duty transient testing of rebuilt 2-stroke MUI diesel bus engines equipped with stabilized zirconia based coatings applied by thermal spray process have shown significant reduction in exhaust opacity relative to a baseline, uncoated engine.

For over a decade, industry prognosticators have been predicting that the use of plastics by automakers would soon surpass the deployment of metals in automobiles, While there is no denying that plastics have made inroads, it recently has become apparent that metal will retain its position as the prime car material for the foreseeable future. One reason for the revised forecast is the development of improved zinc coatings for the automotive industry. Such material as electrogalvanized and Galfan™ are shaping up as steel's saviors when it comes to ensuring that metal will continue to play the major role on car assembly lines. Meanwhile on the other side of the equation, developments in zinc die casting technology have taken the edge off plastics' forward thrust into both functional and decorative car part applications.

Copper and brass radiators have served the automobile industry for many years using traditional fabrication processes. Demand for newer and stronger radiators with lighter weight for the modern vehicles prompted investigation of alternate materials. Properties of zinc alloys and their compatibility with brass suggested these could be used for radiator manufacture. Many zinc alloy compositions were investigated in the initial studies, because a solder alloy has to have many positive attributes. The first screening studies evaluated the ability of the solder to spread over copper and brass surfaces, representing tube, fin, and header materials. The second most important feature was the melting range of the developed alloy. In order to retain the anneal resistance of the fin and temper in the tube it was desirable to have a zinc solder with a melting temperature at 800°F or less.

This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.

Many papers have been written for SAE on electrochemical metallizing, a modern term for “selective” or “brush” plating. These papers have dealt primarily with the aerospace industry, including the use of non-embrittling cadmium LHE® coatings for corrosion protection on aircraft. Shadowed by 30 years of successes in the aerospace industry, electrochemical metallizing corrosion protection in the automotive industry is often overlooked. Specifically, the use of selectively applied zinc coatings for corrosion protection on wheel hubs during manufacture has proven integral at several European automotive manufacturers. In the past, environmental conditions have corroded both the hubs and wheels of automobiles. Quite often the corrosion is in the microscopic gap between the hub and the wheel, which over time causes the wheel to seize and prevents removal. This has been frustrating to both stranded motorists and shop mechanics.

AS PART of its continuing research to improve the die casting process, International Lead Zinc Research Organization, Inc. has prepared a computer program, “Computer-Aided Design for Zinc Die Casting Dies,” which will enable a die caster to design the metal flow system for a die within a matter of minutes—simply and more accurately than ever possible, previously. It is helping convert what has been an art into a science.

The role of zinc die castings in the materials marketplace has changed significantly in the last generation. In response to a shift in the available market, the industry has made major advances intended to improve competitiveness in both traditional and non-traditional areas. Better efficiency and performance have been achieved by the application of new methods and technologies. The ZA alloys, introduced to die casting during the last decade, have markedly expanded the capabilities of both zinc and the die casting process. This paper presents a review of several zinc die castings used in automatic applications.

Zinc die casting products and metal casting processes continue to evolve for the benefit of end users. Through cooperative global research programs continuous improvements are still being made to the broad range of excellent mechanical properties, easy castability and the wide choice of finishes available for zinc die castings. Recent advances will be highlighted with case histories specific to automotive applications.

Because of the drastic chilling involved in die casting and the fact that the solid solubilities of both aluminum and copper in zinc change with temperature, these alloys are subject to some aging changes, one of which is a dimensional change. Both of the alloys undergo a slight shrinkage after casting, which at room temperature is about two-thirds complete in five weeks. It is possible to accelerate this shrinkage by a stabilizing anneal, after which no further changes occur. The recommended stabilizing anneal is 3 to 6 h at 100 °C (212 °F), or 5 to 10 h at 85 °C (185 °F), or 10 to 20 h at 70 °C (158 °F). The time in each case is measured from the time at which the castings reach the annealing temperature. The parts may be air cooled after annealing. Such a treatment will cause a shrinkage (0.0004 in per in) of about two-thirds of the total, and the remaining shrinkage will occur at room temperature during the subsequent few weeks.

Traditional and new zinc-based casting alloys for functional and decorative applications are reviewed. Their compositions and standard alloy specifications are described, and recommendations for casting process selection and prototyping of applications are offered. The information presented shows the versatility achievable with zinc alloys. It is aimed at helping part designers make the most effective use of zinc for their component requirements.

High damping capacity materials are useful in attenuating vibrations in mechanical structures such as functional automotive bracketry. The intrinsic damping properties of zinc alloys have only recently been systematically measured. Low and high frequency damping experiments have been conducted on die cast zinc alloys. and damping capacity has been measured as a function of temperature at high frequencies. The alloys show excellent damping properties over the range from 5 Hertz to a few hundred Hertz. for service applications from 40-80°C (104-176°F).

SIMILAR SPECIFICATIONS—UNS Z33521, former SAE 903, ingot is similar to ASTM B 240-79, Alloy AG40A; and UNS Z33520, former SAE 903, die casting is similar to ASTM B 86-76, Alloy AG40A. UNS Z35530, former SAE 925, ingot is similar to ASTM B 240-79, Alloy AC41A; and UNS Z35531, former SAE 925, die casting is similar to ASTM B 86-82a, Alloy AC41A.